Libreville is the largest city in and capital of Gabon.
You can get to Libreville by plane with Turkish Airlines (direct flights from Istanbul), Lufthansa, Ethiopian Airlines, Air France, Virgin Nigeria (from Lagos via Douala), Gabon Airlines and Air Gabon International (the brand new -private- Air Gabon). SAA flies direct to/from Johannesburg. On a smaller budget, Royal Air Maroc will do the trick (this includes a change of the aircraft in Casablanca, if you come from Europe or America - this can take up to 8 hrs waiting time, but may save you 300 euros. Cameroon Airlines has ceased to exist.
The best way to get around in Libreville if you don't have a car are taxis. For a trip from point A to B (taxis usually go back and forth on one determined route) the fare is negociated with the driver depending on the distance. Fares will double after 21 hrs. From or to the airport 2000 FCFA, or 4000 after 21 hrs. (1000 FCFA = 1.5 euros, 10 000 FCFA = 15 euros). Taxis are less expensive when shared or for short distances (100 to 500 FCFA). You can usually pay 1000 FCFA in the day or 2000 FCFA to not share the taxi and travel a substancial distance (15-minute drive). The cars are not very secure (broken doors, no seatbelts), but if you insist on careful driving, the chauffers will try to oblige. Mini-buses (similar to taxis) are also available for longer routes.
If you can afford it (expensive by European standards), you can rent a car with AVIS. You will not be allowed to leave the town by rented car. Do not expect to arrive at the airport (especially on Sundays and possibly also outside normal business hours (which includes siesta from 12:00 to 15:00)) and find car rental agencies open - pre-arrange! AVIS may be contacted on firstname.lastname@example.org or +241 (1) 74 58 45. While it is reasonably easy by African standards to drive a car yourself in Libreville (provided you know your way around - buy a Gabon guide with maps at the newspaper shop to the right of the international check-in hall), it may not be a very cost-effective solution if you don't plan on moving around a lot.
Libreville's greatest asset is, probably, the seafront (bord de mer) where people gather daily to relax by the Atlantic Ocean. All along the seafront you will find some Gabonese sculptures (some are 20 feet tall!) looking over the beach.
You could also go in Nzeng-ayong to see the Arboretum de Sybang which is a huge tree sanctuary inside Libreville which groups thousands of local species. (But make sure in advance that somebody will be there to open the gate. Once you are inside apply a huge amount of anti mosquito cream on your skin before entering the woods. The people there will remind you - they are very helpful).
The centre ville is also a nice area to visit, in which you are able to enjoy the nearby ocean breeze.
Libreville is a place where people are very laid back and take things slowly. Don't worry about time and plans, and enjoy the city. There is not an exhaustive list of things to do. It is a true multicultural town; its people are very welcoming and will show you the true aspects of the city. The Majestic and Centre Culturel Français (next to Mbolo, the main supermarket) provide both cinema and game rooms; also occasional expositions and concerts. If you'd like to relax on a nice deserted beach, you could go to the Cap Esterias or to Cap Santa Clara, about 30 minutes by car from Libreville. The latter place can be reached by car during the dry season. During the rainy seasons one would need a real 4x4 to get there. The Pointe Denis is another popular spot. It is a peninsula across the bay, close to Libreville. The boat trip takes 25 minutes and cost somewhat between 15 and 20 euros (10 000 and 15 000 fcfa) from the Michel Marine(Navette "Orangina") or Port Mole, Navettes "Beaufort", "Castel" and "Internet". The beach there is beautiful, with a stunning view of Libreville' s seafront.
The city centre is great for shopping, yet surprisingly expensive. Mbolo is the main supermarket, and around the Bord de mer there are several good shops. Keep in mind that between noon and 3 pm everything except the biggest supermarket is closed. In the same area, you'll find the Marche Artisanal where Senegalese merchants sell African instruments, jewelery, clothes, paintings, etc. If you want to see the authentic African side of Libreville, you should go to the gigantic Marché Mont-Bouet. There are bargains a-plenty - but keep an eye on your valuables.
Eating at any good restaurant ends up costing about $24+ for the meal and drinks. Not cheap but it is usually worth it! There are some high end restaurants that can be compared to the best restaurants in Western metropoles. The standard of quality in cheaper restaurants is high. Try one of the three Papa Union restaurants. A great place to have a meal is the restaurant/hotel Excellence in the quartier Ancien Sobraga. It is run by a Belgian guy, and they serve Python a la sauce tomate. Delicious. The main road leading up into the Louis area (from the seafront near Jeanne Eboli Hospital) has a good range of restaurants and clubs. Costa Sylvia Pizzeria makes a very nice Neptune pizza. The Chinese restaurant opposite Le Warhol's is nice too. The good thing about Libreville is that one can eat salads in the restaurants, and there is no need to be afraid of the ice cubes in your drink. The tap water is absolutely ok. L'Emir has very good Lebanese food and the owners are friendly.
The local beers, Regab, Beaufort and Castel are Ok, if you are not too demanding. The local lemonade, Djino, is a real find. It is comparable to Orangina, maybe better. There is no problem to get any imported goods (wine/spirits) if you are prepared to pay.
Clubs, restaurants and bars in the Louis area come to life at night. The main street into Louis starts with Le Warhol's: the decor is in true Pop-Art style, the dance floor and lighting is great, good beats, and the entrance fee gets your first round of drinks. Butterflies doesn't seem like much from the outside, but inside its rustic interior, spacious lounge area and well placed dance floor is well worth the visit, and entrance is free. Pakito Lounge bar is a chilled out spot with pool tables and good vibe. The main street also sports Mirage lounge, Hollywood wine bar and other clubs.
The city is pretty lively at night so get out and enjoy it.
In general do not expect people to speak English (except for some immigrant taxi drivers from West Africa). 80% of the population speak French.